Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

The GEOMON network of Czech catchments provides long-term insights into altered forest biogeochemistry: From acid atmospheric deposition to climate change     

Filip Oulehle  Milan Fischer  Jakub Hruška  Tomáš Chuman  Pavel Krám  Tomáš Navrátil  Miroslav Tesař  Miroslav Trnka 《水文研究》2021,35(5):e14204

In 1994, a network of small catchments (GEOMON) was established in the Czech Republic to determine input–output element fluxes in semi-natural forest ecosystems recovering from anthropogenic acidification. The network consists from 16 catchments and the primary observations of elements fluxes were complemented by monitoring of biomass stock, element pools in soil and vegetation, and the main water balance components. Over last three decades, reductions of SO₂, NO_x and NH₃ emissions were followed by sulphur (S) and nitrogen (N) deposition reductions of 75% and 30%, respectively. Steeper declines of strong acid anion concentrations compared to cations (Ca, Mg, Na, K, NH₄) in precipitation resulted in precipitation pH increase from 4.5 to 5.2 in bulk precipitation and from 4.0 to 5.1 in spruce throughfall. Stream chemistry responded to changes in deposition: S leaching declined. However at majority of catchments soils acted as a net source of S to runoff, delaying recovery. Stream pH increased at acidic streams (pH < 6) and aluminium concentration decreased. Stream nitrate (NO₃) concentration declined by 60%, considerably more than N deposition. Stream NO₃ concentration was tightly positively related to stream total dissolved nitrogen to total phosphorus (P) ratio, suggesting the role of P availability on N retention. Trends in dissolved organic carbon fluxes responded to both acidification recovery and to runoff temporal variation. An exceptional drought occurred between 2014 and 2019. Over this recent period, streamflow decreased by ≈ 40% on average compared to 1990s, due to the increases of soil evaporation and vegetation transpiration by ≈ 30% and declines in precipitation by ≈ 15% on average across the elevational gradient. Sharp decreases of stream runoff at catchments <650 m a.s.l. corresponded to areas of recent forest decline caused by bark beetle infestation on drought stressed spruce forests. Understanding of the interactions among legacies of acidification and eutrophication, drought effects on the water cycle and forest disturbance dynamics is requisite for effective management of forested ecosystems under anthropogenic influence.  相似文献   

薄分子云湍流结构函数的倾角改正及其应用          下载免费PDF全文

钱磊 《天文学报》2021,62(1):7-87

通过结构函数可以测量湍流的能量级联速率.在实际观测中,无法测量分子云中气体的3维速度,这使得其湍流结构函数难以测量.对垂直于视线方向的薄分子云的情形,结构函数Stt2可以通过云核速度弥散(core velocity dispersion,CVD)进行测量,CVD2=1/2Stt2.对此进行推广,对于不垂直于视线方向的薄分子云,CVD2=1/2Stt2(1-1/8cos2θ)R2/3,其中,θ是视线方向与投影方向的夹角,平均投影距离与3维距离之比R可以用第2类椭圆积分E(k,φ)表示为R=2/πE(cosθ,π/2).  相似文献   

一种横观各向同性岩体蠕变模型     

李列列  管俊峰  肖明砾  刘海朝  唐克东 《岩土力学》2020,41(9):2922-2930

层状岩体由于层理面或者结构面的存在，在力学上具有横观各向同性的特点，现有的各向同性蠕变模型难以全面反映横观各向同性岩体的蠕变力学特性。为构建能够反映横观各向同性岩体的三维蠕变模型，以能反映瞬时应变、减速蠕变和稳态蠕变特征的黏弹性Burgers模型为基础，基于常泊松比假定，在三维各向同性蠕变本构方程的基础上，按照算子替换的方法，将横观各向同性柔度矩阵代替各向同性柔度矩阵，并考虑了平行和垂直层理方向岩体蠕变力学行为的差异性，推导了横观各向同性岩体的三维蠕变本构方程。根据本构方程的特点，提出了根据平行和垂直方向岩体蠕变试验结果进行三维蠕变本构模型中蠕变参数的辨识方法。将提出的模型应用于三轴蠕变试验参数辨识，从而获得了一套完整的三维蠕变参数，并与试验结果进行对比分析，从而验证了所提模型与方法的合理性和有效性。进一步，指出了传统蠕变试验设计方案的局限性，给出了横观各向同性材料蠕变试验设计建议。研究成果为研究岩体三维蠕变机制提供了新思路，可对岩体蠕变试验设计提供相应的科研支撑。  相似文献   

基于随机森林模型的农业电子商务浅析——洛川苹果网络销售问题与对策     

张晓涵  马敏飞  杨联安 《地下水》2020,(1):119-122

随着互联网产业的飞速发展,电子商务开始进入农业领域。以电子商务起步较早的"洛川苹果"作为研究对象进行调研。基于随机森林模型的决策树集成算法,对农业网络销售体系整体进行数据分析,模型构建,从问题表象出发挖掘其在不同部分的影响因子,最终基于影响因素解决问题,提出合理化建议:加强农村基础设施建设、健全农村公共服务体系以及完善农村电子商务培训制度等,因地制宜,推进农业电子商务的健康发展。  相似文献   

基于小波变换与神经网络的石羊河流域夏季地温预测模型研究   总被引：1，自引：1，他引：0  

贾东于  李开明  聂晓英  袁春霞  李清峰  高福元 《冰川冻土》2020,42(2):412-422

地温变化在气候反馈效应中起着重要作用， 理解地温及其与影响因素之间的时空关系对预测全球温度变化至关重要。利用1998 - 2017年石羊河流域的逐日常规气象观测资料， 采用小波分析结合BP（Back Propagation）神经网络构建了石羊河流域夏季地温预报模型， 结果表明： 日平均地温预测效果在不同站点均为最佳， 其中预测值和观测值的相关系数均大于0.87， 3 ℃以内的预测概率均大于84%。其中， 民勤地区地温预测效果最好， 预测值和观测值的相关系数达到0.91， 3 ℃以内的预测概率达到86%。日最高地温的预测值与观测值的相关系数高于0.8， 但误差平方和、 标准差较大。永昌地区日最高地温的模拟效果最好， 3 ℃以内的预测概率达到83%。日最低地温的预测与观测值的平均相关系数高于0.66， 3 ℃以内的预报概率高于83%， 但预测值略低。其中， 武威地区日最低地温的预测效果最好， 预测值与观测值的相关系数为0.72， 3 ℃以内的预测概率达到94%。研究成果可为有效弥补干旱、 半干旱区地温观测资料缺失和探讨其与局地气候的关系提供一些参考。  相似文献   

First Multi‐Isotopic (Pb‐Nd‐Sr‐Zn‐Cu‐Fe) Characterisation of Dust Reference Materials (ATD and BCR‐723): A Multi‐Column Chromatographic Method Optimised to Trace Mineral and Anthropogenic Dust Sources     

Aubry Vanderstraeten  Steeve Bonneville  Stefania Gili  Jeroen de Jong  Wendy Debouge  Philippe Claeys  Nadine Mattielli 《Geostandards and Geoanalytical Research》2020,44(2):307-329

Atmospheric dust is an integral component of the Earth system with major implications for the climate, biosphere and public health. In this context, identifying and quantifying the provenance and the processes generating the various types of dust found in the atmosphere is paramount. Isotopic signatures of Pb, Nd, Sr, Zn, Cu and Fe are commonly used as sensitive geochemical tracers. However, their combined use is limited by the lack of (a) a dedicated chromatographic protocol to separate the six elements of interest for low‐mass samples and (b) specific reference materials for dust. Indeed, our work shows that USGS rock reference materials BHVO‐2, AGV‐2 and G‐2 are not applicable as substitute reference materials for dust. We characterised the isotopic signatures of these six elements in dust reference materials ATD and BCR‐723, representatives of natural and urban environments, respectively. To achieve this, we developed a specific procedure for dust, applicable in the 4–25 mg mass range, to separate the six elements using a multi‐column ion‐exchange chromatographic method and MC‐ICP‐MS measurements.  相似文献   

Finite-difference model of land subsidence caused by cluster loads in Zhengzhou,China          下载免费PDF全文

ZHAO Yue-wen  WANG Xiu-yan  LIU Chang-li  LI Bing-yan 《地下水科学与工程》2020,8(1):43-56

Groundwater exploitation has been regarded as the main reason for land subsidence in China and thus receives considerable attention from the government and the academic community.Recently,building loads have been identified as another important factor of land subsidence,but researches in this sector have lagged.The effect of a single building load on land subsidence was neglected in many cases owing to the narrow scope and the limited depth of the additional stress in stratum.However,due to the superposition of stresses between buildings,the additional stress of cluster loads is greater than that of a single building load under the same condition,so that the land subsidence caused by cluster loads cannot be neglected.Taking Shamen village in the north of Zhengzhou,China,as an example,a finite-difference model based on the Biot consolidation theory to calculate the land subsidence caused by cluster loads was established in this paper.Cluster loads present the characteristics of large-area loads,and the land subsidence caused by cluster loads can have multiple primary consolidation processes due to the stress superposition of different buildings was shown by the simulation results.Pore water migration distances are longer when the cluster loads with high plot ratio are imposed,so that consolidation takes longer time.The higher the plot ratio is,the deeper the effective deformation is,and thus the greater the land subsidence is.A higher plot ratio also increases the contribution that the deeper stratigraphic layers make to land subsidence.Contrary to the calculated results of land subsidence caused by cluster loads and groundwater recession,the percentage of settlement caused by cluster loads in the total settlement was 49.43%and 55.06%at two simulated monitoring points,respectively.These data suggest that the cluster loads can be one of the main causes of land subsidence.  相似文献   

节点-场所模型及其应用的研究进展与展望     

陆林  邓洪波 《地理科学》2019,39(1):12-21

系统梳理了节点-场所模型及其应用的相关研究成果,发现已有研究主要集中在利用模型分析枢纽地区节点与场所发展特点、探究枢纽地区类型特点、预测枢纽地区发展潜力等方面。基于高速交通网和互联网的快速发展,提出未来节点-场所模型应用研究的重点方向：开展不同类型交通枢纽地区节点功能和场所功能的协同作用研究,探索旅游地空间节点功能和场所功能的平衡发展路径,探究不同要素流网络中节点城市的节点和场所协同发展,揭示节点-场所模型视域下地域空间演化的特征与规律,构建跨学科多元化的研究方法体系。通过加强节点-场所模型的应用研究,有利于优化地域空间结构,提升地域空间功能,丰富地域空间发展的理论研究,对制定地域空间发展规划具有重要启示。  相似文献   

地缘政治视角下中亚“颜色革命”易发程度分析     

李希雅  王礼茂 《世界地理研究》2019,28(6):42-49

基于地缘政治视角，分析本世纪初发生在原苏联地区“颜色革命”的诱发因素，认为美国根据其地缘战略格局对“颜色革命”发生地存在一定程度的主观选择性，国家内部经济、政治、社会等层面的矛盾也同样作为发生背景。在中亚地缘格局动态分析的基础上，结合中亚五国形势，从时间和空间双重维度对中亚地区未来发生“颜色革命”的可能性进行识别与评判，得出1) 整体来看，中亚近期内爆发“颜色革命”可能性较小，但从长远来看不能掉以轻心。2)土、乌未来稳定可期，塔、吉、哈需谨防“颜色革命”卷土重来。  相似文献